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Few items create more insidious household stains than red wine. Prompt removal will ensure red wine stains do not permanently discolor your grout. Even if the stain is older, you still have some options for removing it.
The best time to remove a red wine stain is when the spill is fresh. Fast action will prevent deep staining of your grout.
Use a paper towel to blot any excess liquid from a fresh spill. Don’t reach for a cloth towel because the red wine will stain the towel.
Read more at: http://www.wikihow.com/Remove-Red-Wine-Stain-from-Grout